Pressure test...
A pressure test will provide your answer quickly as to how/why/where your system is leaking causing coolant boil over; as opposed to throwing good $ at various parts in hopes of fixing problem. W/P, cracked coolant tank or bad o-ring on relief valve are likely suspects based on age but pressure test will reveal issue in short order. Until then, lift up carpet in rear trunk and look for coolant there...
Good luck
