You are correct, the precat sensors adjust the fuel mixture. As blue said, it is related to emissions. Performance is a big factor too though. If you lean out beyond 14.7, you get a more complete burn of the fuel (14.7:1 is stoichiometric but in the real world, especially with our style injectors, it does not result in a complete burn) which will result in more power but also MUCH more heat. This will damage cats, but it can also damage the motor. On the other hand, while you start to lose caloric efficiency as the mixture becomes more rich, you gain the cooling effect from unburned fuel and this helps the motor perform better at sustained high loads. That is why open loop should run a bit on the rich side. The excess fuel will damage cats though, so there's another tradeoff.
You said youre stuck in open loop? I don't see how that's possible if you're not getting a CEL. That's just not how the dme is configured to operate. Additionally, even if you have a ROW tune, the dme is still looking for the precat sensors. If they're not there, the dme will throw a CEL.
If you're really concerned about this, get an aftermarket AFR guage wide wide band sensor. Bosch makes an excellent sensor and the kits are not expensive or difficult to install. They mount into standard sensor bung (m18x1.5) and easy to install. I ran mine up the back side of the engine bay, under the intake plenum, and through the center console tunnel up to the dash, less than an hour start to finish. It will give you a much more meaningful number to use.
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2000 Box Base, Renegade Stage 1 performance mods complete, more to come
When the owners manual says that the laws of physics can't be broken by this car, I took it as a challenge...
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