Let's start with easiest... when was last time the CR2032 battery was replaced in your remotes and do both behave same? Even if "new", who knows how long sat on a retailer shelf so I'd test with digital multi-meter. Same for vehicle battery - how new and have you checked system for any parasitic drains (details below how to gain frunk access). Poor/weak battery conditions (current) can reek all sorts of havoc in DC as well as AC systems.
Central Locking - i.e lock button on dash at top of center consoler... What happens when you depress actual button - does passenger door unlock? And do both lock when depressing other side? If showing locked then manual frunk levers will be locked down too.
Frunk & Trunk access: There's a manual procedure to release the rotating lock cam of manual trunks lever assembly in driver side door sill. You can search for procedure / pictures but basically entails using small "electricians" screwdriver inserted carefully b/w between levers to rotate white locking pin 90 degrees. Use a flashlight. Can also use emergency release pull cord for frunk access - medium size braided cable. If not original owner, check for behind the plug hole as a lot of people relocate there for easier access. Otherwise, you can fish for it under passenger side headlight but otherwise will find behind front passenger side wheel liner.
Good luck... and can help diagnose further but this is good place to start - plus gets you access to frunk and trunk.