I'm painting my rotor hats too and had the same question. I couldn't find a really definitive answer on the Net, but by and large everyone seemed to be using high temp paint. It only makes sense as the rotors can get very hot, even glow! As to gloss or matte finish - that's really up to your personal preference.
Kirk
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2000 Boxster S - Gemballa body kit, GT3 front bumper, JRZ coilovers, lower stress bars
2003 911 Carrera 4S - TechArt body kit, TechArt coilovers, HRE wheels
1986 911 Carrera Targa - 3.2L, Euro pistons, 964 cams, steel slant nose widebody
1975 911S Targa - undergoing a full restoration and engine rebuild
Also In The Garage - '66 912, '69 912, '72 914 Chalon wide body, '73 914
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