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Yes I agree that is coolant. If your a/c system was flat it could be a large leak. It seems possible that when you charged the a/c if the leak was on the side of the condenser, it could have frozen and cracked the plastic side of the radiator. But hitting or scraping the front seems more likely. Has your a/c worked recently? What ever the cause you will definitely need to remove the bumper cover to see what is wrong.
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